Cu中间层SiCp/Al MMCs TLP扩散连接过程分析

采用铜箔作中间层,在连接温度为853 K、无压的条件下进行了瞬间液相连接,对TLP扩散连接过程及其动力学模型进行了分析,并对试验结果进行了的验证.结果表明TLP扩散连接理论模型和试验结果之间还存在着一些差异,对等温凝固过程还需要进一步探讨.分析认为,AlMMCs中大量的晶界、亚晶界、位错等短路扩散通道的存在,直接影响TLP连接过程及其动力学.     

AA1235铝箔坯料的中温相转变

研究了AA1235铝箔坯料中温温度范围内相形成和转变的规律。结果表明,AA1235铝箔坯料在中温温度范围内存在两个相变反应:一个是从铝基体中析出α(AlFeSi)相的脱溶相变,另一个是β′(AlFeSi)→α(AlFeSi)的相变;α(AlFeSi)相的尺寸非常细小,在nm数量级;中间退火过程中Fe、Si元素在铝基体中的固溶度存在一极小值点,即最佳固溶贫化点,该现象的存在是上述两个对固溶度的变化起相反作用的相变过程共同作用的结果。     

Zr3V30Dx氘化物物相及其热解析行为研究

测定了氘化对Zr3V3ODx物相的影响，发现Zr3V30Dx氘化物只有x≥2．0才能稳定存在，由于氘在晶格中的占位不同，随氘含量增加分别出现两种η-碳化物相的氘化物——β相和γ相。对Zr3V3ODx氘化物的热解析行为研究表明：Zr3V30Dx氘化物的稳定性随氘含量的增加而降低，β声相和γ相表现出不同的解析行为，其变化规律与Zr3V3ODx氘化物中的氘占位原则相一致。     

经济型低碳贝氏体复相钢的开发及应用

在实验室研究的基础上，以硅、锰为主元素，并通过热轧工艺的控制和优化，开发了一种低碳贝氏体复相热轧薄板，并在宝钢集团上海梅山钢铁公司热连轧机上进行了屈服强度450MPa级别的贝氏体热轧板的生产试制。结果表明，试验钢的平均屈服强度为500MPa，抗拉强度为590MPa，伸长率为24％，且具有良好的冲击韧性。实验钢已成功用于工程结构，能有效地降低材料消耗，减轻构件重量。     

Thermoelectric properties of mechanically alloyed iron disilicides consolidated by various processes

Mn doped p-type iron disilicide powders have been produced by a mechanical alloying process. As-milled powders were of metastable state and mostly transformed to β-FeSi₂ phase by subsequent isothermal annealing. As-milled powders were consolidated by various processes such as sintering of the cold compact in vacuum, vacuum hot pressing (VHP), and spray drying/atmospheric plasma thermal spraying. Phase transitions during the processes were investigated using XRD, EDS, and SEM. As-consolidated specimens consisted of a mixture of α-Fe₂Si₅ and ε-FeSi phases, which were gradually transformed into a thermoelectric semiconducting α-FeSi₂ phase by subsequent isothermal annealing in the vicinity of 845°C in vacuum. However, some residual α and ε phases remained even after prolonged annealing. Thermoelectric properties were measured as a function of temperature and correlated with phase transformation. They showed optimum values in the vacuum hot pressed specimen due to a higher fraction of β phase and/or higher density.     

气相缓蚀剂的研究现状与展望

从缓蚀剂的缓蚀基团和分子结构方面概述了气相缓蚀剂的研究现状，阐述了气相缓蚀剂的有关缓蚀机理。分析了缓蚀效果的影响因素．讨论了气相缓蚀剂的发展方向．     

稀土镁合金铸造和挤压态组织及力学性能研究

制备了3种不同成分的镁-稀土合金,研究稀土(RE)元素铈(Ce)、钕(Nd)和钇(Y)对镁合金铸态组织、力学性能尤其是高温力学性能的影响.采用光学显微镜(OM)、扫描电子显微镜(SEM)及X射线衍射(XRD)仪等对3种镁-稀土合金组织及相组成进行了分析.稀土元素与镁形成的镁-稀土相分别为Mg12Ce、Mg17Ce2、Mg12Nd、Mg24Y5、Mg41Nd5,主要分布在铸态组织晶界.对3种合金的铸态试样进行了室温力学性能及高温力学性能试验,并与挤压态比较,结果显示:在镁合金中,Nd的强化作用优于Ce,在高温时,Nd和Y共同强化作用优于Nd.     

用偏钛酸作原料制备纳米TiO2粉末以及颗粒相结构与光催化性能关系的研究

米用常温氨水水解TiOSO4过程中加入自制的表面活性剂制备了超细纳米TiO2粉末,用XRD,TEM和比表面仪对不同煅烧温度下的纳米TiO2粉末结构、粒径大小和比表面等进行了表征,研究了纳米TiO2粉末对甲基橙的光催化降解能力。研究表明煅烧温度在400℃～800℃时得到的纳米TiO2粉末呈锐钛矿结构,粒径约为5．5nm～9．6nm,比表面积高达189．45m^2/g;在850℃煅烧后所得的纳米TiO2粉末为锐钛矿与金红石型混晶结构;在l100℃时得到的纳米TiO2粉末为金红石型纳米TiO2粉末,同时微粒出现团聚且粒径变大。光催化实验表明：纳米TiO2粉末的光催化活性与煅烧温度密切相关,850℃煅烧1．5h所制得的混晶结构纳米TiO2粉末表现出较高的光催化活性。与国产商品纳米锐钛矿型TiO2相比,其降解甲基橙的速率约为国产商品纳米TiO2的1倍。     

Ni含量对TiNi形状记忆合金相变行为的影响

用示差扫描热分析仪和光学显微镜系统研究了Ｎｉ含量对ＴｉＮｉ形状记忆合金Ｒ相和Ｍ相相变温度，相变热，热滞的影响。结果表明：在加热和冷却过程中，Ｔｉ－３３．３％Ｎｉ和Ｔｉ－７５．０％Ｎｉ不发生相变；ＴＭ，ΔＭ，ΔＨＭ和ΔＨＲ是Ｎｉ是含量的函数，ＴＲ和ΔＲ基本为一定值，与Ｎｉ含量有关。     

The influence of chromium on mechanical properties of austempered ductile cast iron

An investigation was carried out to examine the influence of microstructure and chromium on the tensile properties and plane strain fracture toughness of austempered ductile cast iron (ADI). The investigation also examined the growth kinetics of ferrite in these alloys. Compact tension and round cylindrical tensile specimens were prepared from ductile cast iron with Cr as well as without Cr. These specimens were then given four different heat treatments to produce four different microstructures. Tensile tests and fracture toughness tests were carried out as per ASTM standards E-8 and E-399. The crack growth mechanism during fracture toughness tests was also determined. The test results indicate that yield strength, tensile strength, and fracture toughness of ADI increases with an increase in the volume fractions of ferrite, and the fracture toughness reaches a peak when the volume fractions of the ferrite are approximately 60% in these alloys. The Cr addition was found to reduce the fracture toughness of ADI at lower hardness levels (<40 HRC); at higher hardness levels (≥40 HRC), the effect of chromium on the fracture toughness was negligible. The crack growth mechanism was found to be a combination of quasi-cleavage and microvoid coalescences, and the crack trajectories connect the graphite nodules along the way.